reviewChemical ReviewsSep 3, 2015GREEN OA

CO 2 Hydrogenation to Formate and Methanol as an Alternative to Photo- and Electrochemical CO 2 Reduction

Dalian University of Technology · Japan Science and Technology Agency · +2 more institutions

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Abstract

In this study, carbon dioxide is one of the end products of combustion, and is not a benign component of the atmosphere. The concentration of CO2 in the atmosphere has reached unprecedented levels and continues to increase owing to an escalating rate of fossil fuel combustion, causing concern about climate change and rising sea levels. In view of the inevitable depletion of fossil fuels, a possible solution to this problem is the recycling of carbon dioxide, possibly captured at its point of generation, to fuels. Researchers in this field are using solar energy for CO2 activation and utilization in several ways: (i) so-called artificial photosynthesis using photo-induced electrons; (ii) bulk electrolysis of a…

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