articleJournal of the American Chemical SocietyApr 25, 2014Closed access

Efficient Water Oxidation Using Nanostructured α-Nickel-Hydroxide as an Electrocatalyst

University of Delaware

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Abstract

Electrochemical water splitting is a clean technology that can store the intermittent renewable wind and solar energy in H2 fuels. However, large-scale H2 production is greatly hindered by the sluggish oxygen evolution reaction (OER) kinetics at the anode of a water electrolyzer. Although many OER electrocatalysts have been developed to negotiate this difficult reaction, substantial progresses in the design of cheap, robust, and efficient catalysts are still required and have been considered a huge challenge. Herein, we report the simple synthesis and use of α-Ni(OH)2 nanocrystals as a remarkably active and stable OER catalyst in alkaline media. We found the highly nanostructured α-Ni(OH)2 catalyst afforded a…

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1,315
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Authors

7

Topics & keywords

Keywords
  • Oxygen evolution
  • Overpotential
  • Tafel equation
  • Electrocatalyst
  • Catalysis
  • Chemistry
  • Water splitting
  • Electrolysis of water
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