Equatorially Coordinated Lanthanide Single Ion Magnets
Changchun Institute of Applied Chemistry · Chinese Academy of Sciences · +1 more institution
Abstract
The magnetic relaxation dynamics of low-coordinate Dy(III) and Er(III) complexes, namely three-coordinate ones with an equatorially coordinated triangle geometry and five-coordinate ones with a trigonal bipyramidal geometry, have been exploited for the first time. The three-coordinate Er-based complex is the first equatorially coordinated mononuclear Er-based single-molecule magnet (SMM) corroborating that simple models can effectively direct the design of target SMMs incorporating 4f-elements.
Citation impact
- FWCI
- 26.60
- Percentile
- 100%
- References
- 37
Authors
6- PZPeng ZhangCorresponding
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, University of Chinese Academy of Sciences
- LZLi Zhang
Chinese Academy of Sciences, University of Chinese Academy of Sciences, Changchun Institute of Applied Chemistry
- CWChao Wang
Chinese Academy of Sciences, Changchun Institute of Applied Chemistry
- SXShufang Xue
University of Chinese Academy of Sciences, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences
- SLShuang‐Yan Lin
Chinese Academy of Sciences, University of Chinese Academy of Sciences, Changchun Institute of Applied Chemistry
Topics & keywords
- Chemistry
- Trigonal bipyramidal molecular geometry
- Magnet
- Lanthanide
- Relaxation (psychology)
- Magnetic relaxation
- Trigonal prismatic molecular geometry
- Coordinate system