articleJournal of the American Chemical SocietyFeb 4, 2015Closed access

Enhanced Photovoltaic Performance of CH 3 NH 3 PbI 3 Perovskite Solar Cells through Interfacial Engineering Using Self-Assembling Monolayer

Zhejiang University · State Key Laboratory of Silicon Materials

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Abstract

Morphology control is critical to achieve high efficiency CH3NH3PbI3 perovskite solar cells (PSC). The surface properties of the substrates on which crystalline perovskite thin films form are expected to affect greatly the crystallization and, thus, the resulting morphology. However, this topic is seldom examined in PSC. Here we developed a facile but efficient method of modifying the ZnO-coated substrates with 3-aminopropanioc acid (C3-SAM) to direct the crystalline evolution and achieve the optimal morphology of CH3NH3PbI3 perovskite film. With incorporation of the C3-SAM, highly crystalline CH3NH3PbI3 films were formed with reduced pin-holes and trap states density. In addition, the work function of the…

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