Covalent Organic Frameworks with High Charge Carrier Mobility

Wan, Shun; Gándara, Felipe; Asano, Atsushi; Furukawa, Hiroyasu; Saeki, Akinori; Dey, Sanjeev K.; Liao, Lei; Ambrogio, Michael W.; Botros, Youssry Y.; Duan, Xiangfeng; Seki, Shu; Stoddart, J. Fraser; Yaghi, Omar M.

doi:10.1021/cm201140r

articleChemistry of MaterialsAug 22, 2011Closed access

Covalent Organic Frameworks with High Charge Carrier Mobility

SWShun Wan FGFelipe Gándara AAAtsushi Asano HFHiroyasu Furukawa ASAkinori Saeki

University of California, Los Angeles · Osaka University · +3 more institutions

Indexed incrossref

Abstract

Two types (imine and boronate) of covalent organic frameworks (COFs) having a porphyrin unit have been synthesized. The two highly crystalline porphyrin COFs (COF-366 and COF-66) display excellent chemical and thermal stability and are permanently porous. Two-dimensional extended layered structures of the two COFs demonstrate very high charge carrier mobility values (8.1 cm2 V−1 s−1).

Citation impact

822

total citations

FWCI: 17.00
Percentile: 100%
References: 46

Citations per year

Authors

13

Topics & keywords

Topics

Keywords

Covalent bond
Porphyrin
Imine
Covalent organic framework
Thermal stability
Materials science
Charge (physics)
Porosity

No related works found for this paper.