reviewChemical ReviewsApr 27, 2016HYBRID OA

Photochemical Approaches to Complex Chemotypes: Applications in Natural Product Synthesis

University of Michigan · Boston University

PubMed
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Abstract

The use of photochemical transformations is a powerful strategy that allows for the formation of a high degree of molecular complexity from relatively simple building blocks in a single step. A central feature of all light-promoted transformations is the involvement of electronically excited states, generated upon absorption of photons. This produces transient reactive intermediates and significantly alters the reactivity of a chemical compound. The input of energy provided by light thus offers a means to produce strained and unique target compounds that cannot be assembled using thermal protocols. This review aims at highlighting photochemical transformations as a tool for rapidly accessing structurally and…

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1,004
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91.27
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100%
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529
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Authors

3

Topics & keywords

Keywords
  • Chemistry
  • Natural product
  • Chemotype
  • Excited state
  • Photochemistry
  • Combinatorial chemistry
  • Absorption (acoustics)
  • Nanotechnology
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