articleEnvironmental Science & TechnologyMay 6, 2015Closed access

Nitrogen-Doped Reduced Graphene Oxide as a Bifunctional Material for Removing Bisphenols: Synergistic Effect between Adsorption and Catalysis

South Central Minzu University · State Ethnic Affairs Commission · +1 more institution

PubMed
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Abstract

Nitrogen modified reduced graphene oxide (N-RGO) was prepared by a hydrothermal method. The nitrogen modification enhanced its adsorption and catalysis ability. For an initial bisphenol concentration of 0.385 mmol L(-1), the adsorption capacity of N-RGO was evaluated as 1.56 and 1.43 mmol g(-1) for bisphenol A (BPA) and 1.43 mmol g(-1) for bisphenol F (BPF), respectively, both of which were about 1.75 times that (0.90 and 0.84 mmol g(-1)) on N-free RGO. N-RGO could activate persulfate, producing strong oxidizing sulfate radicals. The apparent degradation rate constant of BPA on N-RGO was 0.71 min(-1), being about 700 times that (0.001 min(-1)) on N-free RGO. In mixtures of various phenols, the degradation rate…

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Authors

4

Topics & keywords

Keywords
  • Persulfate
  • Chemistry
  • Adsorption
  • Bisphenol A
  • Inorganic chemistry
  • Catalysis
  • Reaction rate constant
  • Graphene
UN Sustainable Development Goals
  • Clean water and sanitation
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