reviewChemical Society ReviewsJan 1, 2016Closed access

Photocatalysis in organic and polymer synthesis

UNSW Sydney · ARC Centre of Excellence in Advanced Molecular Imaging

PubMed
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Abstract

This review, with over 600 references, summarizes the recent applications of photoredox catalysis for organic transformation and polymer synthesis. Photoredox catalysts are metallo- or organo-compounds capable of absorbing visible light, resulting in an excited state species. This excited state species can donate or accept an electron from other substrates to mediate redox reactions at ambient temperature with high atom efficiency. These catalysts have been successfully implemented for the discovery of novel organic reactions and synthesis of added-value chemicals with an excellent control of selectivity and stereo-regularity. More recently, such catalysts have been implemented by polymer chemists to…

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