Mechanism for Broadband White-Light Emission from Two-Dimensional (110) Hybrid Perovskites

The recently discovered phenomenon of broadband white-light emission at room temperature in the (110) two-dimensional organic-inorganic perovskite (N-MEDA)[PbBr4] (N-MEDA = N(1)-methylethane-1,2-diammonium) is promising for applications in solid-state lighting. However, the spectral broadening mechanism and, in particular, the processes and dynamics associated with the emissive species are still unclear. Herein, we apply a suite of ultrafast spectroscopic probes to measure the primary events directly following photoexcitation, which allows us to resolve the evolution of light-induced emissive states associated with white-light emission at femtosecond resolution. Terahertz spectra show fast free carrier…

• AP
  Alfred P. Sloan Foundation
• SU
  Stanford University
• DO
  Division of Graduate Education

  Award: DGE-114747
• AF
  Air Force Office of Scientific Research

  Award: FA9550-14-1-0381