articleOrganometallicsJun 27, 2016HYBRID OA

SambVca 2. A Web Tool for Analyzing Catalytic Pockets with Topographic Steric Maps

King Abdullah University of Science and Technology · Universitat de Girona · +2 more institutions

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Abstract

Developing more efficient catalysts remains one of the primary targets of organometallic chemists. To accelerate reaching this goal, effective molecular descriptors and visualization tools can represent a remarkable aid. Here, we present a Web application for analyzing the catalytic pocket of metal complexes using topographic steric maps as a general and unbiased descriptor that is suitable for every class of catalysts. To show the broad applicability of our approach, we first compared the steric map of a series of transition metal complexes presenting popular mono-, di-, and tetracoordinated ligands and three classic zirconocenes. This comparative analysis highlighted similarities and differences between…

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