articlePure and Applied ChemistryOct 27, 2015HYBRID OA

Standard electrode potentials involving radicals in aqueous solution: inorganic radicals (IUPAC Technical Report)

University of Calgary · National Institute of Standards and Technology · +9 more institutions

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Abstract

Abstract Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 °C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in tables of standard potentials, Gibbs energies of formation, radical p K a ’s, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations.

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Topics & keywords

Keywords
  • Chemical nomenclature
  • Chemistry
  • Radical
  • Aqueous solution
  • Standard electrode potential
  • Gibbs free energy
  • Computational chemistry
  • Physical chemistry
UN Sustainable Development Goals
  • Clean water and sanitation
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