reviewChemical ReviewsAug 31, 2016Closed access

Rationally Designing High-Performance Bulk Thermoelectric Materials

Northwestern University · Beihang University

PubMed
Indexed incrossrefpubmed

Abstract

There has been a renaissance of interest in exploring highly efficient thermoelectric materials as a possible route to address the worldwide energy generation, utilization, and management. This review describes the recent advances in designing high-performance bulk thermoelectric materials. We begin with the fundamental stratagem of achieving the greatest thermoelectric figure of merit ZT of a given material by carrier concentration engineering, including Fermi level regulation and optimum carrier density stabilization. We proceed to discuss ways of maximizing ZT at a constant doping level, such as increase of band degeneracy (crystal structure symmetry, band convergence), enhancement of band effective mass…

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2,277
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88.44
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100%
References
254
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Authors

3

Topics & keywords

Keywords
  • Thermoelectric effect
  • Thermoelectric materials
  • Figure of merit
  • Effective mass (spring–mass system)
  • Condensed matter physics
  • Doping
  • Electron mobility
  • Electronic band structure
UN Sustainable Development Goals
  • Affordable and clean energy
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