articleAdvanced Energy MaterialsJan 25, 2017Closed access

Rational Design of Metal‐Organic Framework Derived Hollow NiCo 2 O 4 Arrays for Flexible Supercapacitor and Electrocatalysis

National University of Singapore · Tongji University

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Abstract

Metal‐organic frameworks (MOFs) are promising porous precursors for the construction of various functional materials for high‐performance electrochemical energy storage and conversion. Herein, a facile two‐step solution method to rational design of a novel electrode of hollow NiCo 2 O 4 nanowall arrays on flexible carbon cloth substrate is reported. Uniform 2D cobalt‐based wall‐like MOFs are first synthesized via a solution reaction, and then the 2D solid nanowall arrays are converted into hollow and porous NiCo 2 O 4 nanostructures through an ion‐exchange and etching process with an additional annealing treatment. The as‐obtained NiCo 2 O 4 nanostructure arrays can provide rich reaction sites and short ion…

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1,008
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44.37
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100%
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Authors

6

Topics & keywords

Keywords
  • Materials science
  • Supercapacitor
  • Electrochemistry
  • Electrode
  • Nanotechnology
  • Electrocatalyst
  • Metal-organic framework
  • Nanostructure
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