Tuning Sn-Catalysis for Electrochemical Reduction of CO 2 to CO via the Core/Shell Cu/SnO 2 Structure
Brown University · Huazhong University of Science and Technology · +2 more institutions
Abstract
Tin (Sn) is known to be a good catalyst for electrochemical reduction of CO2 to formate in 0.5 M KHCO3. But when a thin layer of SnO2 is coated over Cu nanoparticles, the reduction becomes Sn-thickness dependent: the thicker (1.8 nm) shell shows Sn-like activity to generate formate whereas the thinner (0.8 nm) shell is selective to the formation of CO with the conversion Faradaic efficiency (FE) reaching 93% at −0.7 V (vs reversible hydrogen electrode (RHE)). Theoretical calculations suggest that the 0.8 nm SnO2 shell likely alloys with trace of Cu, causing the SnO2 lattice to be uniaxially compressed and favors the production of CO over formate. The report demonstrates a new strategy to tune NP catalyst…
Citation impact
- FWCI
- 22.78
- Percentile
- 100%
- References
- 26
Authors
11Topics & keywords
- Chemistry
- Formate
- Electrochemistry
- Faraday efficiency
- Catalysis
- Bimetallic strip
- Reversible hydrogen electrode
- Tin