reviewChemical Society ReviewsJan 1, 2017HYBRID OA

Metal–organic and covalent organic frameworks as single-site catalysts

SMSven M. J. RoggeABAnastasiya BavykinaJHJulianna HajekHGHermenegildo Garcı́aAIAlma I. Olivos Suarez

Ghent University Hospital · Ghent University · +13 more institutions

PubMed
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Abstract

Heterogeneous single-site catalysts consist of isolated, well-defined, active sites that are spatially separated in a given solid and, ideally, structurally identical. In this review, the potential of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) as platforms for the development of heterogeneous single-site catalysts is reviewed thoroughly. In the first part of this article, synthetic strategies and progress in the implementation of such sites in these two classes of materials are discussed. Because these solids are excellent playgrounds to allow a better understanding of catalytic functions, we highlight the most important recent advances in the modelling and spectroscopic…

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15

Topics & keywords

Topics
Keywords
  • Catalysis
  • Nanotechnology
  • Metal-organic framework
  • Covalent bond
  • Characterization (materials science)
  • Materials science
  • Chemistry
  • Organic chemistry
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