Theory and Calculation of the Phosphorescence Phenomenon
Cherkasy National University · KTH Royal Institute of Technology · +1 more institution
Abstract
Phosphorescence is a phenomenon of delayed luminescence that corresponds to the radiative decay of the molecular triplet state. As a general property of molecules, phosphorescence represents a cornerstone problem of chemical physics due to the spin prohibition of the underlying triplet-singlet emission and because its analysis embraces a deep knowledge of electronic molecular structure. Phosphorescence is the simplest physical process which provides an example of spin-forbidden transformation with a characteristic spin selectivity and magnetic field dependence, being the model also for more complicated chemical reactions and for spin catalysis applications. The bridging of the spin prohibition in…
Citation impact
- FWCI
- 28.64
- Percentile
- 100%
- References
- 290
Authors
3Topics & keywords
- Phosphorescence
- Chemistry
- Chemical physics
- Density functional theory
- Molecule
- OLED
- Photochemistry
- Triplet state