articleAdvanced Functional MaterialsApr 21, 2017Closed access

MoSe 2 ‐Covered N,P‐Doped Carbon Nanosheets as a Long‐Life and High‐Rate Anode Material for Sodium‐Ion Batteries

FNFeier NiuJYJing YangJYJing YangNWNana WangDZDapeng Zhang

Shandong University · Taiyuan University of Technology · +3 more institutions

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Abstract

MoSe 2 grown on N,P‐co‐doped carbon nanosheets is synthesized by a solvothermal reaction followed with a high‐temperature calcination. This composite has an interlayer spacing of MoSe 2 expanded to facilitate sodium‐ion diffusion, MoSe 2 immobilized on carbon nanosheets to improve charge‐transfer kinetics, and N and P incorporated into carbon to enhance its interaction with active species upon cycling. These features greatly improve the electrochemical performance of this composite, as compared to all the controls. It presents a specific capacity of 378 mAh g −1 after 1000 cycles at 0.5 A g −1 , corresponding to 87% of the capacity at the second cycle. Ex situ Raman spectra and high‐resolution transmission…

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Authors

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Topics & keywords

Keywords
  • Materials science
  • Pseudocapacitance
  • Anode
  • Composite number
  • Electrochemistry
  • Carbon fibers
  • Chemical engineering
  • Calcination
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