High Efficiency Photocatalytic Water Splitting Using 2D α‐Fe 2 O 3 /g‐C 3 N 4 Z‐Scheme Catalysts

Photocatalysis is the most promising method for achieving artificial photosynthesis, but a bottleneck is encountered in finding materials that could efficiently promote the water splitting reaction. The nontoxicity, low cost, and versatility of photocatalysts make them especially attractive for this application. This study demonstrates that small amounts of α‐Fe 2 O 3 nanosheets can actively promote exfoliation of g‐C 3 N 4 , producing 2D hybrid that exhibits tight interfaces and an all‐solid‐state Z‐scheme junction. These nanostructured hybrids present a high H 2 evolution rate >3 × 10 4 µmol g ‐1 h ‐1 and external quantum efficiency of 44.35% at λ = 420 nm, the highest value so far reported among the…