articleACS CatalysisMay 10, 2017Closed access

Nest-like NiCoP for Highly Efficient Overall Water Splitting

Wuhan University · Nankai University

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Abstract

The investigation of high-efficiency nonprecious electrocatalysts for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is of great significance for renewable energy technologies. Here, we provide a successive hydrothermal, oxidation, and phosphidation method to fabricate a 3D nest-like ternary NiCoP/carbon cloth (CC) electrocatalyst with superior catalytic activity and stability toward HER/OER. Nest-like NiCoP/CC requires overpotentials of 44 and 62 mV to reach the current density of 10 mA cm–2 in acidic and alkaline media, respectively, toward HER. For OER, the NiCoP/CC exhibits high active and durable performance with an overpotential of 242 mV at current density of 10 mA cm–2 in…

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548
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Authors

5

Topics & keywords

Keywords
  • Overpotential
  • Oxygen evolution
  • Water splitting
  • Electrocatalyst
  • Catalysis
  • Ternary operation
  • Current density
  • Chemical engineering
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