articleAdvanced Energy MaterialsMay 12, 2017Closed access

Defect‐Engineered Ultrathin δ‐MnO 2 Nanosheet Arrays as Bifunctional Electrodes for Efficient Overall Water Splitting

Chinese Academy of Sciences · Nanjing University of Information Science and Technology · +4 more institutions

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Abstract

Recently, defect engineering has been used to intruduce half‐metallicity into selected semiconductors, thereby significantly enhancing their electrical conductivity and catalytic/electrocatalytic performance. Taking inspiration from this, we developed a novel bifunctional electrode consisting of two monolayer thick manganese dioxide (δ‐MnO 2 ) nanosheet arrays on a nickel foam, using a novel in‐situ method. The bifunctional electrode exposes numerous active sites for electrocatalytic rections and displays excellent electrical conductivity, resulting in strong performance for both HER and OER. Based on detailed structure analysis and density functional theory (DFT) calculations, the remarkably OER and HER…

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