articleAngewandte Chemie International EditionMay 19, 2017Closed access

A Bifunctional Hybrid Electrocatalyst for Oxygen Reduction and Evolution: Cobalt Oxide Nanoparticles Strongly Coupled to B,N‐Decorated Graphene

University of Science and Technology of China · Collaborative Innovation Center of Chemistry for Energy Materials · +1 more institution

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Abstract

Abstract The electrocatalyzed oxygen reduction and evolution reactions (ORR and OER, respectively) are the core components of many energy conversion systems, including water splitting, fuel cells, and metal–air batteries. Rational design of highly efficient non‐noble materials as bifunctional ORR/OER electrocatalysts is of great importance for large‐scale practical applications. A new strongly coupled hybrid material is presented, which comprises CoO x nanoparticles rich in oxygen vacancies grown on B,N‐decorated graphene (CoO x NPs/BNG) and operates as an efficient bifunctional OER/ORR electrocatalyst. Advanced spectroscopic techniques were used to confirm formation of abundant oxygen vacancies and strong…

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