articleAdvanced MaterialsJun 19, 2017GREEN OA

Lead‐Free Antiferroelectric Silver Niobate Tantalate with High Energy Storage Performance

State Key Laboratory of New Ceramics and Fine Processing · Tsinghua University · +1 more institution

PubMed
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Abstract

Antiferroelectric materials that display double ferroelectric hysteresis loops are receiving increasing attention for their superior energy storage density compared to their ferroelectric counterparts. Despite the good properties obtained in antiferroelectric La‐doped Pb(Zr,Ti)O 3 ‐based ceramics, lead‐free alternatives are highly desired due to the environmental concerns, and AgNbO 3 has been highlighted as a ferrielectric/antiferroelectric perovskite for energy storage applications. Enhanced energy storage performance, with recoverable energy density of 4.2 J cm −3 and high thermal stability of the energy storage density (with minimal variation of ≤±5%) over 20–120 °C, can be achieved in Ta‐modified AgNbO 3…

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