Recent Advances in Radical C–H Activation/Radical Cross-Coupling
Wuhan University · Jiangxi Normal University
Abstract
Research and industrial interest in radical C-H activation/radical cross-coupling chemistry has continuously grown over the past few decades. These reactions offer fascinating and unconventional approaches toward connecting molecular fragments with high atom- and step-economy that are often complementary to traditional methods. Success in this area of research was made possible through the development of photocatalysis and first-row transition metal catalysis along with the use of peroxides as radical initiators. This Review provides a brief and concise overview of the current status and latest methodologies using radicals or radical cations as key intermediates produced via radical C-H activation. This Review…
Citation impact
- FWCI
- 67.12
- Percentile
- 100%
- References
- 320
Authors
7Topics & keywords
- Chemistry
- Radical
- Nucleophile
- Radical ion
- Radical cyclization
- Radical substitution
- Radical disproportionation
- Atom economy
- Industry, innovation and infrastructure
Funding
- NNNational Natural Science Foundation of ChinaAwards: 21402217, 21390400, 21272180, 2109343, 21302148
- MOMinistry of Education of the People's Republic of ChinaAwards: IRT1030, 20120141130002
- MOMinistry of Science and Technology of the People's Republic of ChinaAwards: 2011CB808600, 2013CB834804, 2012YQ120060, 2012CB725302
- SAState Administration of Foreign Experts Affairs