Influence of Lattice Polarizability on the Ionic Conductivity in the Lithium Superionic Argyrodites Li 6 PS 5 X (X = Cl, Br, I)

X by controlling the fractional occupancy of the halide anions (X = Cl, Br, I). Ultrasonic speed of sound measurements are used to quantify the variation in the lattice stiffness and Debye frequencies. In combination with electrochemical impedance spectroscopy and neutron diffraction, these results show that the lattice softness has a striking influence on the ionic transport: the softer bonds lower the activation barrier and simultaneously decrease the prefactor of the moving ion. Due to the contradicting influence of these parameters on ionic conductivity, we find that it is necessary to tailor the lattice stiffness of materials in order to obtain an optimum ionic conductivity.

• JL
  Justus Liebig Universität Gießen
• DL
  Diamond Light Source