articleJournal of the American Chemical SocietyJul 31, 2017Closed access

Stabilizing Cesium Lead Halide Perovskite Lattice through Mn(II) Substitution for Air-Stable Light-Emitting Diodes

Chinese Academy of Sciences · ShanghaiTech University · +5 more institutions

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Abstract

All-inorganic cesium lead halide perovskite (CsPbX3, X = Cl, Br, and I) quantum dots (QDs), possessing high photoluminescence quantum yields and tunable color output, have recently been endowed great promise for high-performance solar cells and light-emitting diodes (LEDs). Although moisture stability has been greatly improved through separating QDs with a SiO2 shell, the practical applications of CsPbX3 QDs are severely restricted by their poor thermal stability, which is associated with the intrinsically low formation energies of perovskite lattices. In this regard, enhancing the formation energies of perovskite lattices of CsPbX3 QDs holds great promise in getting to the root of their poor thermal…

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