Dynamic multinuclear sites formed by mobilized copper ions in NO x selective catalytic reduction

X-ray vision spies copper on the move Copper ions in zeolites help remove noxious nitrogen oxides from diesel exhaust by catalyzing their reaction with ammonia and oxygen. Paolucci et al. found that these copper ions may move about during the reaction (see the Perspective by Janssens and Vennestrom). Zeolite catalysts generally fix metals in place while the reacting partners flow in and out of their cagelike structures. In this case, though, x-ray absorption spectroscopy suggested that the ammonia was mobilizing the copper ions to pair up as they activated oxygen during the catalytic cycle. Science , this issue p. 898 ; see also p. 866

• NS
  National Science Foundation

  Awards: 1552517-CBET, award313208, 1258715-CBET, award313207, 1258690-CBET, award313206
• UD
  U.S. Department of Energy

  Awards: DE-AC02-06CH11357, award313210
• CI
  Cummins Incorporated

  Award: award335981