articleAdvanced Energy MaterialsSep 18, 2017Closed access

Single‐Atom Catalysts: Emerging Multifunctional Materials in Heterogeneous Catalysis

HZHuabin ZhangGLGuigao LiuLSLi ShiJYJinhua Ye

National Institute for Materials Science · Tianjin University

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Abstract

Abstract Supported metal nanoparticles are the most widely investigated heterogeneous catalysts in catalysis community. The size of metal nanostructures is an important parameter in influencing the activity of constructed catalysts. Especially, as coordination unsaturated metal atoms always work as the catalytically active centers, decreasing the particle size of the catalyst can greatly boost the specific activity per metal atom. Single‐atom catalysts (SACs), containing single metal atoms anchored on supports, represent the utmost utilization of metallic catalysts and thus maximize the usage efficiency of metal atom. However, with the decreasing of particle size, the surface free energy increases obviously,…

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Topics & keywords

Keywords
  • Catalysis
  • Materials science
  • Atom (system on chip)
  • Metal
  • Dispersion (optics)
  • Nanotechnology
  • Nanoparticle
  • Particle (ecology)
UN Sustainable Development Goals
  • Affordable and clean energy
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