articleAngewandte Chemie International EditionSep 19, 2017HYBRID OA

Covalent Triazine Frameworks via a Low‐Temperature Polycondensation Approach

Huazhong University of Science and Technology · Tianjin University · +3 more institutions

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Abstract

Abstract Covalent triazine frameworks (CTFs) are normally synthesized by ionothermal methods. The harsh synthetic conditions and associated limited structural diversity do not benefit for further development and practical large‐scale synthesis of CTFs. Herein we report a new strategy to construct CTFs (CTF‐HUSTs) via a polycondensation approach, which allows the synthesis of CTFs under mild conditions from a wide array of building blocks. Interestingly, these CTFs display a layered structure. The CTFs synthesized were also readily scaled up to gram quantities. The CTFs are potential candidates for separations, photocatalysis and for energy storage applications. In particular, CTF‐HUSTs are found to be…

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