articleJournal of the American Chemical SocietyDec 28, 2017Closed access

Shape-Control of Pt–Ru Nanocrystals: Tuning Surface Structure for Enhanced Electrocatalytic Methanol Oxidation

University of Science and Technology of China · Changchun Institute of Applied Chemistry · +1 more institution

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Abstract

Despite the fact that both electrochemical experiments and density functional theory calculations have testified to the superior electrocatalytic activity and CO-poisoning tolerance of platinum–ruthenium (PtRu) alloy nanoparticles toward the methanol oxidation reaction (MOR), the facet-dependent electrocatalytic properties of PtRu nanoparticles are scarcely revealed because it is extremely difficult to synthesize well-defined facets-enclosed PtRu nanocrystals. Herein, we for the first time report a general synthesis of ultrathin PtRu nanocrystals with tunable morphologies (nanowires, nanorods, and nanocubes) through a one-step solvothermal approach and a systematic investigation of the structure-directing…

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