articleNature CommunicationsJan 8, 2019GOLD OA

Chromium-ruthenium oxide solid solution electrocatalyst for highly efficient oxygen evolution reaction in acidic media

Chinese Academy of Sciences · University of Chinese Academy of Sciences · +3 more institutions

PubMed
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Abstract

Abstract The development of active, acid-stable and low-cost electrocatalysts for oxygen evolution reaction is urgent and challenging. Herein we report an Iridium-free and low ruthenium-content oxide material (Cr 0.6 Ru 0.4 O 2 ) derived from metal-organic framework with remarkable oxygen evolution reaction performance in acidic condition. It shows a record low overpotential of 178 mV at 10 mA cm −2 and maintains the excellent performance throughout the 10 h chronopotentiometry test at a constant current of 10 mA cm −2 in 0.5 M H 2 SO 4 solution. Density functional theory calculations further revealed the intrinsic mechanism for the exceptional oxygen evolution reaction performance, highlighting the influence…

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