articleAdvanced MaterialsJan 31, 2019Closed access

Extended Electrochemical Window of Solid Electrolytes via Heterogeneous Multilayered Structure for High‐Voltage Lithium Metal Batteries

Chinese Academy of Sciences · Beijing National Laboratory for Molecular Sciences · +1 more institution

PubMed
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Abstract

Abstract In response to the call for safer high‐energy‐density storage systems, high‐voltage solid‐state Li metal batteries have attracted extensive attention. Therefore, solid electrolytes are required to be stable against both Li anode and high‐voltage cathodes; nevertheless, the requirements still cannot be completely satisfied. Herein, a heterogeneous multilayered solid electrolyte (HMSE) is proposed to broaden electrochemical window of solid electrolytes to 0–5 V, through different electrode/electrolyte interfaces to overcome the interfacial instability problems. Oxidation‐resistance poly(acrylonitrile) (PAN) is in contact with the cathode, while reduction tolerant polyethylene glycol diacrylate contacts…

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