articleAdvanced MaterialsFeb 4, 2019Closed access

Highly Efficient Blue Fluorescent OLEDs Based on Upper Level Triplet–Singlet Intersystem Crossing

South China University of Technology · Chinese Academy of Sciences · +3 more institutions

PubMed
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Abstract

Abstract Purely organic electroluminescent materials, such as thermally activated delayed fluorescent (TADF) and triplet–triplet annihilation (TTA) materials, basically harness triplet excitons from the lowest triplet excited state (T 1 ) to realize high efficiency. Here, a fluorescent material that can convert triplet excitons into singlet excitons from the high‐lying excited state (T 2 ), referred to here as a “hot exciton” path, is reported. The energy levels of this compound are determined from the sensitization and nanosecond transient absorption spectroscopy measurements, i.e., small splitting energy between S 1 and T 2 and rather large T 2 –T 1 energy gap, which are expected to impede the internal…

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