reviewChemical Society ReviewsJan 1, 2019GREEN OA

Multifunctional porous hydrogen-bonded organic framework materials

The University of Texas at San Antonio · National Institute of Standards and Technology · +1 more institution

PubMed
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Abstract

Hydrogen-bonded organic frameworks (HOFs) represent an interesting type of polymeric porous materials that can be self-assembled through H-bonding between organic linkers. To realize permanent porosity in HOFs, stable and robust open frameworks can be constructed by judicious selection of rigid molecular building blocks and hydrogen-bonded units with strong H-bonding interactions, in which the framework stability might be further enhanced through framework interpenetration and other types of weak intermolecular interactions such as ππ interactions. Owing to the reversible and flexible nature of H-bonding connections, HOFs show high crystallinity, solution processability, easy healing and purification. These…

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