articleNature CommunicationsFeb 21, 2019GOLD OA

Promoting electrocatalytic CO2 reduction to formate via sulfur-boosting water activation on indium surfaces

Xiamen University · Collaborative Innovation Center of Chemistry for Energy Materials · +2 more institutions

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Abstract

Abstract Electrocatalytic reduction of CO 2 to fuels and chemicals is one of the most attractive routes for CO 2 utilization. Current catalysts suffer from low faradaic efficiency of a CO 2 -reduction product at high current density (or reaction rate). Here, we report that a sulfur-doped indium catalyst exhibits high faradaic efficiency of formate (>85%) in a broad range of current density (25–100 mA cm −2 ) for electrocatalytic CO 2 reduction in aqueous media. The formation rate of formate reaches 1449 μmol h −1 cm −2 with 93% faradaic efficiency, the highest value reported to date. Our studies suggest that sulfur accelerates CO 2 reduction by a unique mechanism. Sulfur enhances the activation of water,…

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