articleAccounts of Chemical ResearchFeb 28, 2019Closed access

Assembling-Induced Emission: An Efficient Approach for Amorphous Metal-Free Organic Emitting Materials with Room-Temperature Phosphorescence

East China University of Science and Technology

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Abstract

Pure organic emitting materials with room-temperature phosphorescence (RTP), showing large Stokes shifts with long emitting lifetime, low preparation cost, good processability, and wide applications in analysis, bioimaging, organic light emitting diode, and so forth, have been drawing great attentions recently. Related to the design strategy for metal-free RTP materials, the phosphors containing heavy atoms (Br, I, etc.) and other heteroatoms (O, S, etc.) to facilitate the singlet-to-triplet intersystem crossing (ISC) to populate the triplet are usually employed. Besides this factor, the pathways of nonradiative relaxation are inhibited as much as possible. Crystalline packing was the commonly used strategy to…

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Authors

3

Topics & keywords

Keywords
  • Phosphorescence
  • Amorphous solid
  • Intersystem crossing
  • Materials science
  • Supramolecular chemistry
  • Nanotechnology
  • OLED
  • Phosphorescent organic light-emitting diode
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