articleChemistry of MaterialsApr 4, 2019GREEN OA

Surface Termination Dependent Work Function and Electronic Properties of Ti 3 C 2 T x MXene

Helmholtz-Zentrum Berlin für Materialien und Energie · Humboldt-Universität zu Berlin · +3 more institutions

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Abstract

MXenes, an emerging family of 2D transition metal carbides and nitrides, have shown promise in various applications, such as energy storage, electromagnetic interference shielding, conductive thin films, photonics, and photothermal therapy. Their metallic nature, wide range of optical absorption, and tunable surface chemistry are the key to their success in those applications. The physical properties of MXenes are known to be strongly dependent on their surface terminations. In this study, we investigated the electronic properties of Ti3C2Tx for different surface terminations, as achieved by different annealing temperatures, with the help of photoelectron spectroscopy, inverse photoelectron spectroscopy, and…

Citation impact

642
total citations
FWCI
21.20
Percentile
100%
References
43
Citations per year

Authors

8

Topics & keywords

Keywords
  • Work function
  • MXenes
  • X-ray photoelectron spectroscopy
  • Density functional theory
  • Materials science
  • Annealing (glass)
  • Electronic structure
  • Density of states
UN Sustainable Development Goals
  • Affordable and clean energy
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