reviewChemical Society ReviewsJan 1, 2019BRONZE OA

Mixed-metal metal–organic frameworks

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Abstract

Mixed-metal MOFs are metal-organic frameworks that contain at least 2 different metal ions as nodes of their frameworks. They are prepared relatively easily by either a one-pot synthesis with a synthesis mixture containing the different metals, or by a post-synthetic ion-exchange method by soaking a monometallic MOF in a concentrated solution of a different (but compatible) metal-ion. More difficult is the accurate characterization of these materials. Is the formed product a mixture of monometallic MOFs or indeed a MOF with different metallic nodes? Are the metals randomly distributed or do they form domains? What is the oxidation state of the metals? How do the metals mutually influence each other, and impact…

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