articleJournal of the American Chemical SocietyApr 11, 2019HYBRID OA

Metal–Organic Frameworks as Catalysts for Organic Synthesis: A Critical Perspective

Stockholm University · University of Zurich

PubMed
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Abstract

Recent advances in organic chemistry and materials chemistry have enabled the porosity of new materials to be accurately controlled on the nanometer scale. In this context, metal-organic frameworks (MOFs) have rapidly become one of the most attractive classes of solid supports currently under investigation in heterogeneous catalysis. Their unprecedented degree of tunability gives MOFs the chance to succeed where others have failed. The past decade has witnessed an exponential growth in the complexity of new structures. MOFs with a variety of topologies and pore sizes show excellent stability across wide ranges of pH and temperature. Even the controlled insertion of defects, to alter the MOF's properties in a…

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787
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Authors

4

Topics & keywords

Keywords
  • Chemistry
  • Metal-organic framework
  • Context (archaeology)
  • Nanotechnology
  • Catalysis
  • Rational design
  • Homogeneous
  • Olefin metathesis
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