reviewChemical ReviewsJul 11, 2019Closed access

Enantioenriched Helicenes and Helicenoids Containing Main-Group Elements (B, Si, N, P)

Centre National de la Recherche Scientifique · Institut des Sciences Chimiques de Rennes · +1 more institution

PubMed
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Abstract

In this review, we discuss the rich chemistry of helicenes and helicenoids containing main-group elements. Enantioenriched helicenic derivatives containing main-group elements B, Si, N, and P, either incorporated within the helical backbone or grafted to it, will be thoroughly presented. We will describe their synthesis, resolution, and asymmetric synthesis, their structural features, electronic and chiroptical properties, and emission, together with other photochemical properties and applications.

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