Ultrahigh Performance in Lead-Free Piezoceramics Utilizing a Relaxor Slush Polar State with Multiphase Coexistence

Owing to growing environmental concerns, the development of lead-free piezoelectrics with comparable performance to the benchmark Pb(Zr,Ti)O3 (PZT) becomes of great urgency. However, a further enhancement of lead-free piezoelectrics based on existing strategies has reached a bottleneck. Here we achieve a slush polar state with multiphase coexistence in lead-free potassium–sodium niobate (KNN) piezoceramics, which shows a novel relaxor behavior, i.e., frequency dispersion at the transition between different ferroelectric phases. It is very different from the conventional relaxor behavior which occurs at the paraelectric–ferroelectric phase transition. We obtain an ultrahigh piezoelectric coefficient (d33) of…

• MO
  Ministry of Education - Singapore

  Award: MOE2017-T2-1-129
• NN
  National Natural Science Foundation of China

  Award: 51722208