The Three‐Dimensional Dendrite‐Free Zinc Anode on a Copper Mesh with a Zinc‐Oriented Polyacrylamide Electrolyte Additive

Abstract Rechargeable aqueous zinc‐ion batteries have been considered as a promising candidate for next‐generation batteries. However, the formation of zinc dendrites are the most severe problems limiting their practical applications. To develop stable zinc metal anodes, a synergistic method is presented that combines the Cu‐Zn solid solution interface on a copper mesh skeleton with good zinc affinity and a polyacrylamide electrolyte additive to modify the zinc anode, which can greatly reduce the overpotential of the zinc nucleation and increase the stability of zinc deposition. The as‐prepared zinc anodes show a dendrite‐free plating/stripping behavior over a wide range of current densities. The symmetric…

• NN
  National Natural Science Foundation of China

  Award: No.21671200 and No.21571189