reviewChemical ReviewsOct 2, 2019GREEN OA

A Theory/Experience Description of Support Effects in Carbon-Supported Catalysts

Centre National de la Recherche Scientifique · Université Toulouse III - Paul Sabatier · +5 more institutions

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Abstract

The support plays an important role for supported metal catalysts by positioning itself as a macromolecular ligand, which conditions the nature of the active site and contributes indirectly but also sometimes directly to the reactivity. Metal species such as nanoparticles, clusters, or single atoms can be deposited on carbon materials for various catalytic reactions. All the carbon materials used as catalyst support constitute a large family of compounds that can vary both at textural and at structural levels. Today, the recent developments of well-controlled synthesis methodologies, advanced characterization techniques, and modeling tools allow one to correlate the relationships between metal/support/reactant…

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