articleACS NanoOct 4, 2019Closed access

Flexible and Free-Standing Ti 3 C 2 T x MXene@Zn Paper for Dendrite-Free Aqueous Zinc Metal Batteries and Nonaqueous Lithium Metal Batteries

Shandong University · University of Science and Technology of China · +1 more institution

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Abstract

Dendrite growth of metal anodes is one of the key hindrances for both secondary aqueous metal batteries and nonaqueous metal batteries. In this work, a freestanding Ti3C2Tx MXene@Zn paper is designed as both zinc metal anode and lithium metal anode host to address the issue. The binder-free Ti3C2Tx MXene@Zn paper exhibits merits of good mechanical flexibility, high electronic conductivity, hydrophilicity, and lithiophilicity. The crystal growth mechanism of Zn metal on common Zn foil and Ti3C2Tx MXene@Zn composite is also studied. It is found that the Ti3C2Tx MXene@Zn paper can effectively suppress the dendrite growth of Zn, enabling reversible and fast Zn plating/stripping kinetics in an aqueous electrolyte.…

Citation impact

542
total citations
FWCI
35.47
Percentile
100%
References
39
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Authors

7

Topics & keywords

Keywords
  • Faraday efficiency
  • Materials science
  • Anode
  • Dendrite (mathematics)
  • Metal
  • Zinc
  • Nucleation
  • Electrolyte
UN Sustainable Development Goals
  • Affordable and clean energy
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