reviewChemical Society ReviewsJan 1, 2019GREEN OA

Colloidal metal–organic framework particles: the pioneering case of ZIF-8

Institut Català de Nanociència i Nanotecnologia · Barcelona Institute of Science and Technology

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Abstract

The production of metal-organic frameworks (MOFs) in the form of colloids has brought a paradigm shift in the design of new functional porous materials. Along with their intrinsic interest as porous solids, and contrary to their bulk powder counterparts, colloidal MOF particles can additionally be dispersed, shaped, functionalized, transformed and assembled in a controlled manner, conferring them further properties and applications. In this regard, zeolitic imidazolate framework-8 (ZIF-8) has become a pioneering MOF constituent of colloidal science. Today, the understanding of the role of synthetic parameters, learned after one decade of research, enables the production of monodisperse colloidal ZIF-8…

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