Chemistry with Electrochemically Generated N-Centered Radicals
Xiamen University · Collaborative Innovation Center of Chemistry for Energy Materials
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Abstract
Evolution without the need for chemical oxidants. In addition, cathodic solvent reduction can continuously generate a low concentration of base, which facilitates anodic substrate oxidation. Such a mechanistic paradigm obviates the need for stoichiometric strong bases and avoids base-promoted decomposition of sensitive substrates or products. Furthermore, electrode materials can also be adjusted to control the reaction outcome, as demonstrated by the synthesis of N-heteroaromatics and the corresponding N-oxides from biaryl ketoximes.
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1,035
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Authors
2Topics & keywords
Topics
Keywords
- Chemistry
- Radical
- Electrosynthesis
- Electrochemistry
- Electrophile
- Radical ion
- Hydrogen atom abstraction
- Radical substitution
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