articleJournal of the American Chemical SocietyDec 5, 2019Closed access

Tuning the Coordination Environment in Single-Atom Catalysts to Achieve Highly Efficient Oxygen Reduction Reactions

JZJinqiang ZhangYZYufei ZhaoCCChen ChenCCChen ChenYHYucheng Huang

University of Technology Sydney · National Taiwan University · +4 more institutions

PubMed
Indexed incrossrefpubmed

Abstract

Designing atomically dispersed metal catalysts for oxygen reduction reaction (ORR) is a promising approach to achieve efficient energy conversion. Herein, we develop a template-assisted method to synthesize a series of single metal atoms anchored on porous N,S-codoped carbon (NSC) matrix as highly efficient ORR catalysts to investigate the correlation between the structure and their catalytic performance. The structure analysis indicates that an identical synthesis method results in distinguished structural differences between Fe-centered single-atom catalyst (Fe-SAs/NSC) and Co-centered/Ni-centered single-atom catalysts (Co-SAs/NSC and Ni-SAs/NSC) because of the different trends of each metal ion in forming a…

Citation impact

981
total citations
FWCI
26.86
Percentile
100%
References
46
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Authors

13

Topics & keywords

Keywords
  • Chemistry
  • Catalysis
  • Oxygen atom
  • Reduction (mathematics)
  • Oxygen reduction reaction
  • Oxygen
  • Atom (system on chip)
  • Oxygen reduction
UN Sustainable Development Goals
  • Affordable and clean energy
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