articleNature CommunicationsDec 12, 2019GOLD OA

Amorphization activated ruthenium-tellurium nanorods for efficient water splitting

Soochow University · University of California, Irvine · +1 more institution

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Abstract

Abstract Pursuing active and durable water splitting electrocatalysts is of vital significance for solving the sluggish kinetics of the oxygen evolution reaction (OER) process in energy supply. Herein, theoretical calculations identify that the local distortion-strain effect in amorphous RuTe 2 system abnormally sensitizes the Te-pπ coupling capability and enhances the electron-transfer of Ru-sites, in which the excellent inter-orbital p-d transfers determine strong electronic activities for boosting OER performance. Thus, a robust electrocatalyst based on amorphous RuTe 2 porous nanorods (PNRs) is successfully fabricated. In the acidic water splitting, a-RuTe 2 PNRs exhibit a superior performance, which only…

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Authors

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Topics & keywords

Keywords
  • Oxygen evolution
  • Water splitting
  • Electrocatalyst
  • Materials science
  • Amorphous solid
  • Nanorod
  • Ruthenium
  • Chemical physics
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