articleEnvironmental Science & TechnologyFeb 17, 2020HYBRID OA

Persulfate-Based Advanced Oxidation: Critical Assessment of Opportunities and Roadblocks

Korea University · École Polytechnique Fédérale de Lausanne · +2 more institutions

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Abstract

Reports that promote persulfate-based advanced oxidation process (AOP) as a viable alternative to hydrogen peroxide-based processes have been rapidly accumulating in recent water treatment literature. Various strategies to activate peroxide bonds in persulfate precursors have been proposed and the capacity to degrade a wide range of organic pollutants has been demonstrated. Compared to traditional AOPs in which hydroxyl radical serves as the main oxidant, persulfate-based AOPs have been claimed to involve different in situ generated oxidants such as sulfate radical and singlet oxygen as well as nonradical oxidation pathways. However, there exist controversial observations and interpretations around some of…

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Authors

3

Topics & keywords

Keywords
  • Persulfate
  • Peroxydisulfate
  • Oxidizing agent
  • Chemistry
  • Singlet oxygen
  • Hydrogen peroxide
  • Hydroxyl radical
  • Advanced oxidation process
UN Sustainable Development Goals
  • Clean water and sanitation
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