articleSmallMar 17, 2020Closed access

Multidimension‐Controllable Synthesis of MOF‐Derived Co@N‐Doped Carbon Composite with Magnetic‐Dielectric Synergy toward Strong Microwave Absorption

Fudan University · Collaborative Innovation Center of Chemistry for Energy Materials

PubMed
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Abstract

Metal-organic framework (MOF) is highly desirable as a functional material owing to its low density, tunable pore size, and diversity of coordination formation, but limited by the poor dielectric properties. Herein, by controlling the solvent and mole ratio of cobalt/linker, multidimension-controllable MOF-derived nitrogen-doped carbon materials exhibit tunable morphology from sheet-, flower-, cube-, dodecahedron- to octahedron-like. Tunable electromagnetic parameters of Co@N-doped carbon composites (Co@NC) can be obtained and the initial MOF precursor determines the distribution of carbon framework and magnetic cobalt nanoparticles. Carbonized Co@NC composites possess the following advantages: i) controllable…

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