articleAngewandte Chemie International EditionApr 6, 2020Closed access

Ultrathin ZnIn 2 S 4 Nanosheets Anchored on Ti 3 C 2 T X MXene for Photocatalytic H 2 Evolution

Nanyang Technological University · Nanjing University of Science and Technology · +2 more institutions

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Abstract

Abstract Photocatalysts derived from semiconductor heterojunctions that harvest solar energy and catalyze reactions still suffer from low solar‐to‐hydrogen conversion efficiency. Now, MXene (Ti 3 C 2 T X ) nanosheets (MNs) are used to support the in situ growth of ultrathin ZnIn 2 S 4 nanosheets (UZNs), producing sandwich‐like hierarchical heterostructures (UZNs‐MNs‐UZNs) for efficient photocatalytic H 2 evolution. Opportune lateral epitaxy of UZNs on the surface of MNs improves specific surface area, pore diameter, and hydrophilicity of the resulting materials, all of which could be beneficial to the photocatalytic activity. Owing to the Schottky junction and ultrathin 2D structures of UZNs and MNs, the…

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